DK142624B - Fremgangsmåde til fremstilling af en metanrig gas. - Google Patents
Fremgangsmåde til fremstilling af en metanrig gas. Download PDFInfo
- Publication number
- DK142624B DK142624B DK162178AA DK162178A DK142624B DK 142624 B DK142624 B DK 142624B DK 162178A A DK162178A A DK 162178AA DK 162178 A DK162178 A DK 162178A DK 142624 B DK142624 B DK 142624B
- Authority
- DK
- Denmark
- Prior art keywords
- catalyst
- reactor
- gas
- temperature
- methanization
- Prior art date
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title description 49
- 238000000034 method Methods 0.000 title description 33
- 230000008569 process Effects 0.000 title description 28
- 239000003054 catalyst Substances 0.000 description 97
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 62
- 239000007789 gas Substances 0.000 description 50
- 230000002211 methanization Effects 0.000 description 38
- 229910052759 nickel Inorganic materials 0.000 description 30
- 238000002474 experimental method Methods 0.000 description 29
- 238000006243 chemical reaction Methods 0.000 description 26
- 230000015572 biosynthetic process Effects 0.000 description 15
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 11
- 229910002091 carbon monoxide Inorganic materials 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 238000000746 purification Methods 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 230000009849 deactivation Effects 0.000 description 7
- 238000002309 gasification Methods 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000295 fuel oil Substances 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000002754 natural gas substitute Substances 0.000 description 2
- 239000010742 number 1 fuel oil Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241001274197 Scatophagus argus Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- MAYPHUUCLRDEAZ-UHFFFAOYSA-N chlorine peroxide Chemical compound ClOOCl MAYPHUUCLRDEAZ-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000002641 tar oil Substances 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 210000000689 upper leg Anatomy 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Industrial Gases (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK162178AA DK142624B (da) | 1978-04-13 | 1978-04-13 | Fremgangsmåde til fremstilling af en metanrig gas. |
| GB7912395A GB2018818B (en) | 1978-04-13 | 1979-04-09 | Process for preparing a methane-rich gas |
| DE19792914806 DE2914806A1 (de) | 1978-04-13 | 1979-04-11 | Verfahren zur herstellung eines methanreichen gases |
| FR7909354A FR2422612A1 (fr) | 1978-04-13 | 1979-04-12 | Procede de preparation d'un gaz riche en methane |
| JP4444079A JPS54135709A (en) | 1978-04-13 | 1979-04-13 | Manufacture of methane enriched gas |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK162178AA DK142624B (da) | 1978-04-13 | 1978-04-13 | Fremgangsmåde til fremstilling af en metanrig gas. |
| DK162178 | 1978-04-13 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DK162178A DK162178A (en]) | 1979-10-14 |
| DK142624B true DK142624B (da) | 1980-12-01 |
| DK142624C DK142624C (en]) | 1981-08-03 |
Family
ID=8106617
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK162178AA DK142624B (da) | 1978-04-13 | 1978-04-13 | Fremgangsmåde til fremstilling af en metanrig gas. |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS54135709A (en]) |
| DE (1) | DE2914806A1 (en]) |
| DK (1) | DK142624B (en]) |
| FR (1) | FR2422612A1 (en]) |
| GB (1) | GB2018818B (en]) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59175442A (ja) * | 1983-03-23 | 1984-10-04 | Toyo Eng Corp | メタンを含むガスの製造法 |
| GB0805020D0 (en) | 2008-03-18 | 2008-04-16 | Al Chalabi Rifat | Active reformer |
| EP2370203A2 (en) | 2008-12-31 | 2011-10-05 | Shell Oil Company | Adiabatic reactor and a process and a system for producing a methane-rich gas in such adiabatic reactor |
| CN102317237A (zh) * | 2008-12-31 | 2012-01-11 | 国际壳牌研究有限公司 | 制备富甲烷气体的方法 |
| CN102482174B (zh) | 2009-08-03 | 2014-09-10 | 国际壳牌研究有限公司 | 联产过热蒸汽和甲烷的方法 |
| EP2462088B1 (en) | 2009-08-03 | 2016-07-20 | Shell Oil Company | Process for the production of methane |
| DE102010037980A1 (de) * | 2010-10-05 | 2012-04-05 | Thyssenkrupp Uhde Gmbh | Verfahren und Vorrichtung zur Erzeugung eines methanreichen Gases aus Synthesegas |
| RU2458105C2 (ru) * | 2010-11-03 | 2012-08-10 | ООО "Центр КОРТЭС" | Способ подготовки газового топлива |
| CN102660339B (zh) * | 2012-04-27 | 2014-04-30 | 阳光凯迪新能源集团有限公司 | 基于生物质气化与甲烷化的燃气-蒸汽高效联产工艺及系统 |
| EP3362689A1 (en) * | 2015-10-16 | 2018-08-22 | R.E.M. Holding S.r.l. | Connecting element for connecting a blade to the hub in an industrial axial fan, and blade system comprising said connecting element |
| EP4493652A1 (en) * | 2022-03-14 | 2025-01-22 | Topsoe A/S | Conversion of methanol to a hydrocarbon product stream |
| WO2024200537A1 (en) | 2023-03-29 | 2024-10-03 | Hitachi Zosen Inova Ag | Process and plant for the production of a methane-containing synthetic natural gas stream |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR646782A (fr) * | 1927-12-24 | 1928-11-15 | Cie Continentale Pour La Fabri | Procédé particulièrement destiné à l'enrichissement en methans, ou méthanisation de gaz industriels |
| DE2432887B2 (de) * | 1974-07-09 | 1980-08-28 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Erzeugung eines mit Erdgas austauschbaren Gases |
| AR205595A1 (es) * | 1974-11-06 | 1976-05-14 | Haldor Topsoe As | Procedimiento para preparar gases rico en metano |
| AT328186B (de) * | 1974-12-23 | 1976-03-10 | Vianova Kunstharz Ag | Verfahren zur herstellung verbesserter selbststabilisierender polymerisatdispersionen in organischen flussigkeiten |
-
1978
- 1978-04-13 DK DK162178AA patent/DK142624B/da not_active IP Right Cessation
-
1979
- 1979-04-09 GB GB7912395A patent/GB2018818B/en not_active Expired
- 1979-04-11 DE DE19792914806 patent/DE2914806A1/de active Granted
- 1979-04-12 FR FR7909354A patent/FR2422612A1/fr active Granted
- 1979-04-13 JP JP4444079A patent/JPS54135709A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FR2422612B1 (en]) | 1984-09-28 |
| JPS54135709A (en) | 1979-10-22 |
| DE2914806C2 (en]) | 1988-07-21 |
| FR2422612A1 (fr) | 1979-11-09 |
| GB2018818B (en) | 1982-06-23 |
| DE2914806A1 (de) | 1979-10-18 |
| DK142624C (en]) | 1981-08-03 |
| GB2018818A (en) | 1979-10-24 |
| DK162178A (en]) | 1979-10-14 |
| JPS6236503B2 (en]) | 1987-08-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PBP | Patent lapsed | ||
| PBP | Patent lapsed |